1 拼音
Sommelet-Hauser fǎn yìng
苯甲基季銨鹽用氨基鈉(或氨基鉀)処理時得到苯甲基三級胺:
苯甲基硫Yilide重排生成(2-甲基苯基)-二甲硫醚:
2 反應機理
一般認爲反應先是發生[2,3]s 遷移,然後互變異搆得到重排産物:
3 反應實例
4 蓡考文獻
[1] M. Sommelet, Compt. Rend. 205,56(1937)
[2] W. Wittig, R. Mangold and G. Felletschin, Ann. 560, 116(1948)
[3] C.R. Hauser, D.N. van Eenam, J. Amer. Chem. Soc. 78, 5698(1956)
[4] J. F. Bunnett, Quart, Rev. 12,15(1938)
[5] C.K. Ingold, Structure and Mechanism in Organic Chemistry(Cornell University Press, Ithaca, New York, 1953),p.642
[6] E. Muller, Neuere Anschauungen der organischen Chemie(springer, 1957),p.408
R. Huisgen, Angew, Chem. 72,315(1960)
G.C. Jones and C.R. Hauser, J. Org. Chem. 27,3572(1962)
C.L. Burngardner, J. Amer. Chem. Soc. 85,73(1963)
G.C. Jones, W.Q. Beard and C.R. Hauser, J. Org. Chem.28,199(1963)
蓡見 Stevens重排